5. Curtly Ambrose v Australia – 189:

Curtly Ambrose features yet again in this list. This time against Australia. Unlike these days, West Indies in the 90s would give the Aussies a tough fight with their pacers in the form of Ambrose, Courtney Walsh and Ian Bishop and a strong batting line. Curtly has taken 189 wickets at an average of 21.41 against the Aussies, the most by any bowler.